Micellar Studies of Magnesium Caprylate after Addition of Hydroxy Additives Using Ion-Selective Electrode

Authors

  • Dushyant Pareek  Department of Chemistry, S.D. Govt. College, Vidya Nagar, Beawar Rajasthan, India
  • Narendra Nirwan  Department of Chemistry, S.D. Govt. College, Vidya Nagar, Beawar Rajasthan, India
  • Chandresh Pareek  Department of Chemistry, S.D. Govt. College, Vidya Nagar, Beawar Rajasthan, India

Keywords:

Ion-Selective Electrode, EMF, Lipophilic hydromicelle, Hydrophilic oleomicelle, Ice-berg, palisade layers

Abstract

Magnesium soap of caprylic acid was prepared and a cell was set up for the measurement of EMF of the cell having soap solutions in methanol water solvent system with the aid of Ion-Selective Electrode. The Critical Micelle Concentration of soap solutions was determined by graphical method. The effect of hydroxy additives on CMC values of referred soap solution has been studied by using electrometric method with the aid of ion selective electrode. The values of free energy change are negative indicating the spontaneity of cell reaction and decreases with increasing soap concentration while increases with the increase methanol concentration in solvent mixture.

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International Journal of Scientific Research in Chemistry

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Published

2016-03-25

Issue

Volume 1, Issue 2, -2016

Section

Research Articles

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How to Cite

[1]
Dushyant Pareek, Narendra Nirwan, Chandresh Pareek, " Micellar Studies of Magnesium Caprylate after Addition of Hydroxy Additives Using Ion-Selective Electrode, International Journal of Scientific Research in Chemistry(IJSRCH), ISSN : 2456-8457, Volume 1, Issue 2, pp.15-22, -2016.