Synthesis and Characterization of Zinc Sulfide and Zinc-Iron Sulfide Nanoparticles from Zinc(II) Dithiocarbamate Complexes
Keywords:
Zinc(II) Dithiocarbamate, Zinc Sulfide, Zinc-Iron Sulfide, Nanoparticles; Single Source PrecursorsAbstract
Bis(N-(pyrrol-2-ylmethyl)-N-(2-phenylethyl) dithiocarbamato-S, S?) zinc(II) (1) and bis(N-methylferrocenyl-N-(2-phenylethyl) dithiocarbamato-S, S?) zinc(II) (2) have been synthesized and characterized by elemental analysis and spectroscopy (IR and UV-vis). Complexes 1 and 2 have been used as precursors for the preparation of zinc sulfide and zinc-iron sulfide nanoparticles. Morphological characterization of nanoparticles was carried out using TEM.
References
- Z. Leka, D. Voja, M. Kosovi, N. Latinovic, M. Dakovic, A. Visnjevac, Synthesis, structure and antifungal activities of noval Co, Mo and Pt complexes with triammonium N, N-diacetatedithiocarbamate, Polyhedron. 80 (2014) 233- 242:
- G.N. Kaludjerovic, V.M. Ojinovic, S.R. Trifunovic, I.M. Hodzic and T.J. Sabo, Synthesis and characterization of trisbutyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]-cobalt(III)seskvitoluene, J. Serb. Chem. Soc. 67 (2002) 123-126:
- R. Abu-El-Halawa, S.A. Zabin, Removal efficiency of Pb, Cd, Cu and Zn from polluted water using dithiocarbamate ligands, J. Taiba Univ. Sci. (2015) 1- 9:
- M. Gong, A. Kiokeminde, N.Kumar, H.Zhao and S.Ren, Ionic-passivated FeS2 photocapactors for energy conversion and storage, Chem. Commun. 49 (2013) 9260-9262:
- N. Tokyo, K. Azkio, J Pn. Kokai Pat. 7855478 C1.C23 C15/00, (1978):
- N. Tokya, JPn. Kokai pat. 75130378 C1 H0 1L CO 1B, (1975):
- D. J. Asunskis, I.L. Boltin, A. T. W Rolde, A.M. Zachary and L.Hanley, Lead sulfide nanocrystals-polymer composition for optoelectronic applications, Macromol.
- Symp. 268 (2008) 33-37:
- S. Khalid, E. Ahmed, M.A. Malik, S. Abu bakar, Y. Khan and P.O. Brien, Synthesis of pyrite thin films and transition metal doped pyrite thin films by aerosol-assisted chemical vapour deposition, New. J. Chem. 39 (2015) 1013-1021:
- E. Sathiyaraj, G. Gurumoorthy and S. Thirumaran, Nickel(II) dithiocarbamate complexes containing the pyrrole moiety for sensing anions and synthesis of nickel sulfide and nickel oxide nanoparticles, New. J. Chem. 39 (2015) 5336-5349:
- N.L. Pickett and P.O. Brien, Synthesis of semiconductor nanoparticles using single-molecular precursors, Chem. Rec. 1 (2001) 467-479:
- N. Srinivasan, S. Thirumaran, Effect of pyridine as a ligand in precursor on morphology of CdS nanoparticles, Superlattices Microstruct. 51 (2012) 912-920:
- S. Rengaraj, S. Venkatraj, S.H. Jec, Y.H. Kim, C. Tai, E. Repo, A. Koistienen, A. Ferancova, M. Sillpaa, Self-Assembled Mesoporous Hierarchial-like In2S3 Hallow Microspheres Composed of Nanofibers and Nanosheets and their Photocatalytic Activity, Langumuir 27 (2011) 352- 358:
- R. Chauhan, A. Kumar, R.P. Chaudhary, Photocatalytic degradation of methylene blue with Cu doped ZnS nanoparticles, J. Lumin. 145 (2014) 6-12:
- S. Lee, D. Song, D. Kim, J. Lee, S. Kim, I.Y. Park, Y.D. Choi, Effects of synthesis temperature on particle size/shape and photoluminescence characteristics of ZnS:Cu nanocrystals, Mater. Lett. 58 (2004) 342.
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