Binuclear Copper (II) Complexes with Hydroxyimine Ligand

Authors

  • Shikha Kumari   University Department of Chemistry, B. N. Mandal University, Madhepura, Bihar, India

Keywords:

Binuclear copper (II) complexes, Spectral study, Hydroximine ligands

Abstract

A series of binuclear copper (II) complexes of the type, [Cu2LX2] (X=Cl-, Br-, NO3-, ClO4-) has been synthesized by reacting an ethanolic solution of inner complex of copper (II), [Cu (L)] with ethanolic solution of copper (II) salts in equimolar quantities. H2L is the Schiff base ligand, 2, 9-dihydroxyimino-4, 7-diaza-5, 6:-methylbenzo-3,8-dimethyl-3, 7- diaza-3,7-deccadiene. Characterization has been done on the basis of spectral, conductivity and magnetic studies.

References

  1. J. M. Lehn, Supramolecular Chemistry Concepts and Perspectives, Wiley-VCH, Weinheim, Germany, 1st edition, 1995
  2. R. E. Mewis and S. J. Archibald, “Biomedical applications of macrocyclic ligand complexes,” Coordination Chemistry Reviews, vol. 254, no. 15-16, pp. 1686–1712, 2010.
  3. K. B. Shiu, S. A. Liu, and G. H. Lee, “One-pot conditional self-assembly of multicopper metallacycles,” Inorganic Chemistry, vol. 49, no. 21, pp. 9902–9908, 2010.
  4. M. J. Al-Jeboori and A. S. Al-Shihri, “An unusual coordination of potentially binucleating N2O Schiff base ligands with rhenium,” Journal of Saudi Chemical Society, vol. 5, no. 3, p. 341, 2001.
  5. M. J. Al-Jeboori, H. A. Hasan, and W. A. Jaafer Al-Sa'Idy, “Formation of polymeric chain assemblies of transition metal complexes with a multidentate Schiff-base,” Transition Metal Chemistry, vol. 34, no. 6, pp. 593–598, 2009.
  6. S. Sreedaran, K. S. Bharathi, A. K. Rahiman et al., “Synthesis, electrochemical, catalytic and antimicrobial activities of novel unsymmetrical macrocyclic dicompartmental binuclear nickel(II) complexes,” Polyhedron, vol. 27, no. 7, pp. 1867–1874, 2008.
  7. M. J. Al-Jeboori, A. S. A. Abdul Rahman, and S. Atia, “Synthesis and spectral studies on cobalt(II), nickel(II), copper(II), palladium(II), platinum(II, IV), zinc(II), cadmium(II) and mercury(II) complexes of (1,2-diaminoethane-N,N¢-bis(2-butylidine-3onedioxime,” Ibn Al-Haitham Journal for Pure and Applied Science, vol. 18, no. 2, pp. 51–67, 2005.
  8. M. M. Aly, A. O. Baghlaf, and N. S. Ganji, “Linkage isomerism of the oximato group: the characterization of some mono- and binuclear square planar nickel (II) complexes of vicinal oxime-imine ligands,” Polyhedron, vol. 4, no. 7, pp. 1301–1309, 1985.
  9. Celik Kumali, Ulukanli Zeynep, Tumer Mehmet and Sarin Selahattin, Spectroscopic Characterization of Oxime ligand and their complexes, Spectroscopic Letters, 36 (1-2) 51-70 (2003)
  10. H.C. Rai, J. Chakraborti and B. Sahoo, Metal Complexes of Co (II), Ni (II) and Cu (II) with ligands derived from the reactions of diamines with 3-hydroximino-butane-2-one, Ind.J.Chem. 18A 242-246 (1989)   
  11. Avinash Kumar, Niraj Kumar, Kuldeep Singh and Kushmendu Singh, Synthesis of macrocyclic complex of Cr(III), Mn (II) , Fe (III), Co (II), Ni (II) and Cu (II) containing a tetraoxaoctaazacyclo tetra- decaene ligand Int. J.Curr.Res. 8 (10) 40455 – 40447 (2016)
  12. Howlader M. B. H., Islam M.S. and Karim M.R., Synthesis of some 16- membered microcyclic complexes of Cr (III), Mn (II), Fe (III) Co (II), Ni (II) and Cu (II)., Ind.J.Chem.39 A 407-409 (2000).

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Published

2021-06-30

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Section

Research Articles

How to Cite

[1]
Shikha Kumari , " Binuclear Copper (II) Complexes with Hydroxyimine Ligand, International Journal of Scientific Research in Chemistry(IJSRCH), ISSN : 2456-8457, Volume 6, Issue 3, pp.27-30, May-June-2021.