Synthesis and Characterization of Cobalt Sulfide and Cobalt-Iron Sulfide Nanoparticles from cobalt(III) Dithiocarbamate Complexes

Authors

  • G. Gurumoorthy  Department of Chemistry, Bharath Institute of Higher Education and Research, Chennai, Tamil Nadu, India
  • R. Hema  Department of Chemistry, Bharath Institute of Higher Education and Research, Chennai, Tamil Nadu, India
  • M. Sundararajan   Department of Chemistry, Bharath Institute of Higher Education and Research, Chennai, Tamil Nadu, India

Keywords:

Cobalt(III) dithiocarbamate; cobalt sulfide; cobalt-iron sulfide; nanoparticles; single source precursors

Abstract

Tris(N-(pyrrol-2-ylmethyl)-N-butyldithiocarbamato-S,S?) cobalt(III) (1), bis(N-methylferrocenyl-N-(2-phenylethyl) dithiocarbamato-S,S?) nickel(II) (2) complexes were used as single source precursors for the preparation of cobalt sulfide and cobalt-iron sulfide nanoparticles. Morphological characterization of nanoparticles was carried out using TEM and the optical properties by UV-Vis and photoluminescence spectroscopic techniques. The elemental compositions of the nanoparticles were confirmed by energy dispersive X-ray spectroscopy. IR spectral studies on nanoparticles confirm the presence of capping agent (triethylenetetramine).

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Published

2020-12-30

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Section

Research Articles

How to Cite

[1]
G. Gurumoorthy, R. Hema, M. Sundararajan , " Synthesis and Characterization of Cobalt Sulfide and Cobalt-Iron Sulfide Nanoparticles from cobalt(III) Dithiocarbamate Complexes, International Journal of Scientific Research in Chemistry(IJSRCH), ISSN : 2456-8457, Volume 5, Issue 6, pp.78-82, November-December-2020.