N, O Donor Schiff Base Polymeric Complexes : Synthesis, Characterization, and Antimicrobial Studies

Authors

  • Dr. Rakesh Ranjan  M.Sc., Ph.D. Department of Chemistry, B.R.A. Bihar University, Muzaffarpur, Bihar, India

Keywords:

Elemental Analysis, IR, NMR Spectrum Data, Schiff Base, Polymeric Complexes

Abstract

With a Schiff base ligand created from the condensation of 2,4-dihydroxy acetophenone and p-phenylene diamine, a number of novel polymeric complexes of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) were created. These complexes were then characterised by elemental analysis, IR, and NMR spectrum data. The Schiff base and its polymeric complexes have been investigated for its antibacterial properties.

References

  1. A. S. Shakeel, N. V. Kalyane, S. R. Karjgi, and M. L. Ahmed, “Synthesis and antibacterial activity of new Schiff's bases,” International Journal of Pharmacy and Life Sciences, no. 5, pp. 246–249, 2010.
  2. R. Johari, G. Kumar, and S. Singh, “Synthesis and antibacterial activity of M (II) Schiff base complex,” Journal of the Indian Council of Chemists, vol. 26, pp. 23–27, 2009.
  3. J. H. Pandya and M. K. Shah, “Synthesis and antimicrobial properties of transition metal complexes of novel Schiff base ligand derived from 5-bromosalicyldehyde,” Journal of the Indian Council of Chemists, vol. 26, no. 2, pp. 109–112, 2009.
  4. S. Varghese and M. K. Muraleedharan Nair, “Spectroscopic and antimicrobial studies of some 2-hydroxybenzilidene-3-aminophenol complexes,” Research Journal of Pharmaceutical, Biological and Chemical Sciences, vol. 1, no. 2, pp. 347–353, 2010.
  5. S. Kumar, D. N. Dhar, and P. N. Saxena, “Applications of metal complexes of Schiff bases-a review,” Journal of Scientific and Industrial Research, vol. 68, no. 3, pp. 181–187, 2009.
  6. F. M. Morad, M. M. E. L. Ajaily, and S. Ben-Gweirif, “Preparation, physical characterization and antibacterial activity of Ni (II) Schiff base complex,” Journal of Science and Its Applications, vol. 1, pp. 72–78, 2007.
  7. P. Singh and R. K. S. Dhakarey, “Synthesis, characterization and antimicrobial studies of metal complexes with Schiff bases derived from 2-thienyl glyoxal,” Rasayan Journal of Chemistry, vol. 2, no. 4, pp. 869–874, 2009.
  8. J. Salimon, N. Salih, E. Yousif, A. Hameed, and H. Ibraheem, “Synthesis, characterization and biological activity of Schiff bases of 2, 5-dimercapto-1,3,4-thiadiazole,” Australian Journal of Basic and Applied Sciences, vol. 4, no. 7, pp. 2016–2021, 2010.
  9. K. S. S. Lamani, O. Kotresh, M. A. Phaniband, and J. C. Kadakol, “Synthesis, characterization and antimicrobial properties of Schiff bases derived from condensation of 8-formyl-7-hydroxy-4-methylcoumarin and substituted triazole derivatives,” E-Journal of Chemistry, vol. 6, supplement 1, pp. S239–S246, 2009.
  10. A. M. Hamil, K. M. Khalifa, A. Al-Houni, and M. M. El-Ajaily, “Synthesis, spectroscopic investigation and antiactivity activity of Schiff base complexes of cobalt (II) and copper (II) ions,” Rasayan Journal of Chemistry, vol. 2, no. 2, pp. 261–266, 2009.
  11. A. P. Mishra and N. Sharma, “Synthesis, characterization, X-ray and thermal studies of some Schiff base metal complexes,” Journal of the Indian Council of Chemists, vol. 26, pp. 125–129, 2009.
  12. T. Rosu, S. Pasculescu, V. Lazar, C. Chifiriuc, and R. Cernat, “Copper(II) complexes with ligands derived from 4-amino-2,3-dimethyl-1-phenyl-3-pyrazolin-5-one: synthesis and biological activity,” Molecules, vol. 11, no. 11, pp. 904–914, 2006.
  13. N. S. Gwaram, H. M. Ali, M. A. Abdulla et al., “Antibacterial evaluation of some Schiff bases derived from 2-acetylpyridine and their metal complexes,” Molecules, vol. 17, no. 5, pp. 5952–5971, 2012.
  14. A. P. Mishra, R. Mishra, R. Jain, and S. Gupta, “Synthesis of new VO(II), Co(II), Ni(II) and Cu(II) complexes with isatin-3- chloro-4-floroaniline and 2-pyridinecarboxylidene-4 aminoantipyrine and their antimicrobial studies,” The Korean Society of Mycology, vol. 40, no. 1, pp. 20–26, 2012.
  15. A. S. Munde, A. N. Jagdale, S. M. Jadhav, and T. K. Chondhekar, “Synthesis, characterization and thermal study of some transition metal complexes of an asymmetrical tetradentate Schiff base ligand,” Journal of the Serbian Chemical Society, vol. 75, no. 3, pp. 349–359, 2010.
  16. U. K. Singh, S. N. Pandeya, S. K. Sethia et al., “Synthesis and biological evaluation of some sulfonamide Schiff's bases,” International Journal of Pharmaceutical Sciences and Drug Research, vol. 2, no. 3, pp. 216–218, 2010.
  17. V. Reddy, N. Patil, and S. D. Angadi, “Synthesis, characterization and antimicrobial activity of Cu(II), Co(II) and Ni(II) complexes with O, N, and S donor ligands,” E-Journal of Chemistry, vol. 5, no. 3, pp. 577–583, 2008.
  18. S. Joshi, V. Pawar, and V. Uma, “Synthesis, characterization and biological studies of Schiff bases metal complexes Co (II), Zn (II), Ni (II), and Mn (II) derived from amoxicillin trihydrate with various aldehydes,” International Journal of Pharma and Bio Sciences, vol. 2, no. 1, pp. 240–250, 2011.
  19. A. K. Mapari and K. V. Mangaonkar, “Synthesis, characterization and antimicrobial activity of mixed Schiff base ligand complexes of transition metal (II) ions,” International Journal of ChemTech Research, vol. 3, no. 1, pp. 477–482, 2011.
  20. P. Venkatesh, “Synthesis, charecterisation and anti microbial activity of various Schiff base complex of zinc(II) and copper (II) ions,” Asian Journal of Pharmaceutical and Health Sciences, vol. 1, pp. 8–11, 2011.
  21. M. Revanasiddappa, T. Suresh, S. Khasim, S. C. Raghavendray, C. Basavaraja, and S. D. Angadi, “Transition metal complexes of 1, 4(2′-hydroxyphenyl-1-yl) di-imino azine: synthesis, characterization and antimicrobial studies,” E-Journal of Chemistry, vol. 5, no. 2, pp. 395–403, 2008.

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Published

2016-03-25

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Section

Research Articles

How to Cite

[1]
Dr. Rakesh Ranjan, " N, O Donor Schiff Base Polymeric Complexes : Synthesis, Characterization, and Antimicrobial Studies, International Journal of Scientific Research in Chemistry(IJSRCH), ISSN : 2456-8457, Volume 1, Issue 2, pp.26-31, -2016.