Treatment of Thermogravimetric Kinetic Equations to Copolymer Derived from 4,4’-dihydroxybiphenyl

Authors

  • Pawan P. Kalbende  Department of Chemistry, Jagdamba Mahavidyalaya, Achalpur, Amravati, India

Keywords:

Condensation polymerization, Synthesis, Spectroscopic characterization, Thermogravimetry, Biphenol.

Abstract

4,4’-Dihydroxybiphenyl-4,4’-Diaminodiphenyl ether-Formaldehyde (4,4’-DBP-4,4’-DDE-F-I) copolymer has been synthesized by acid catalyzed (2M HCl) condensation polymerization between 4,4’-Dihydroxybiphenyl (4,4’-DBP) and 4,4’-Diaminodiphenyl ether (4,4’-DDE) with Formaldehyde (F). The structure of synthesized copolymer has been elucidated on the basis of elemental analysis and spectral techniques viz. UV–Visible, FT-IR and 1H-NMR spectroscopy. Thermal analysis has been carried out for studying its thermal degradation behavior and kinetics. Thermal degradation curve has been discussed with minute details for each decomposition step. Friedman, Chang, Sharp-Wentworth, Freeman-Carroll and Coat Redfern methods have been implemented to evaluate the kinetic parameters such as Ea, n and ln(z).

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International Journal of Scientific Research in Chemistry

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Published

2020-09-30

Issue

Volume 5, Issue 5, September-October-2020

Section

Research Articles

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How to Cite

[1]
Pawan P. Kalbende, " Treatment of Thermogravimetric Kinetic Equations to Copolymer Derived from 4,4’-dihydroxybiphenyl , International Journal of Scientific Research in Chemistry(IJSRCH), ISSN : 2456-8457, Volume 5, Issue 5, pp.22-31, September-October-2020.